Contamination risk and drinking water protection for a large-scale managed aquifer recharge site in a semi-arid karst region,Jordan     

Julian Xanke  Tanja Liesch  Nadine Goeppert  Jochen Klinger  Niklas Gassen  Nico Goldscheider 《Hydrogeology Journal》2017,25(6):1795-1809

Karst aquifers in semi-arid regions are particularly threatened by surface contamination, especially during winter seasons when extremely variable rainfall of high intensities prevails. An additional challenge is posed when managed recharge of storm water is applied, since karst aquifers display a high spatial variability of hydraulic properties. In these cases, adapted protection concepts are required to address the interaction of surface water and groundwater. In this study a combined protection approach for the surface catchment of the managed aquifer recharge site at the Wala reservoir in Jordan and the downstream Hidan wellfield, which are both subject to frequent bacteriological contamination, is developed. The variability of groundwater quality was evaluated by correlating contamination events to rainfall, and to recharge from the reservoir. Both trigger increased wadi flow downstream of the reservoir by surface runoff generation and groundwater seepage, respectively. A tracer test verified the major pathway of the surface flow into the underground by infiltrating from pools along Wadi Wala. An intrinsic karst vulnerability and risk map was adapted to the regional characteristics and developed to account for the catchment separation by the Wala Dam and the interaction of surface water and groundwater. Implementation of the proposed protection zones for the wellfield and the reservoir is highly recommended, since the results suggest an extreme contamination risk resulting from livestock farming, arable agriculture and human occupation along the wadi. The applied methods can be transferred to other managed aquifer recharge sites in similar karstic environments of semi-arid regions.  相似文献   

Photosystem II herbicide pollution in Hong Kong and its potential photosynthetic effects on corals     

Shaw CM  Lam PK  Mueller JF 《Marine pollution bulletin》2008,57(6-12):473-478

Photosystem II (PSII) herbicides have been shown to affect the photosynthesis of corals at low, environmentally relevant concentrations. The recent detection of the PSII herbicide Irgarol-1051 in coastal waters of Hong Kong at concentrations above the EC(50) for reduction of photosynthesis of corals prompted further investigation into the extent of PSII herbicide pollution in coral reefs of Hong Kong. Snap-shot and passive samples were taken from coral reef sites and evaluated via HPLC/MS-MS and a novel bioanalytical technique. Low concentrations (less than 10 ng L(-1)) of diuron and atrazine were found at all study sites. Extracts from these samples concentrated by a factor of 10 were found to reduce the photosynthetic yield of zooxanthellae. It appears unlikely that herbicide pollution is a key issue in isolation but may act synergistically with other stressors to reduce the viability of Hong Kong's coral reefs. The study has also demonstrated the feasibility of combining sample extraction techniques with a coral specific bioanalytical technique for a sensitive assessment of risks associated with herbicide exposure in corals.  相似文献   

Chemistry of Halogen Oxides in the Troposphere: Comparison of Model Calculations with Recent Field Data   总被引：2，自引：0，他引：2  

Jochen Stutz  Kai Hebestreit  Björn Alicke  Ulrich Platt 《Journal of Atmospheric Chemistry》1999,34(1):65-85

Reactive halogen species (RHS = X, XO, HOX, OXO; X = Cl, Br, I) are known to have an important influence on the chemistry in the polar boundary layer (BL), where they are responsible for ozone depletion events in spring. Recent field campaigns at Mace Head, Ireland, and the Dead Sea, Israel, identified for the first time iodine oxide (IO) at mixing ratios of up to 6.6 ppt and 90 ppt bromine oxide (BrO), respectively, by DOAS also at lower latitudes. These results intensified the discussion about the role of the RHS in the mid-latitude BL.Photochemical box model calculations show that the observed IO mixing ratios can destroy ~0.45 ppb ozone per hour. This is comparable to the rates of the known O₃-loss processes in the boundary layer. The model studies also reveal that IO, at these levels, has a strong influence on the BL photochemistry, increasing the OH/HO₂- and the NO₂/NO - ratios. In combination these changes lead to a reduction of the photochemical ozone formation, which - in addition - reduces ozone mixing ratios by up to 0.15 ppb/h.The studies for the Dead Sea case give no information on the heterogeneous process responsible for the bromine release, but they show that a total of 2 – 4 ppb of total bromine have to be released to explain the observed complete depletion of 60 ppb ozone in 2 – 3 hours.  相似文献   

Geographic Information Systems and the Law. Mapping the Legal Frontiers: By George Cho.     

Jochen Albrecht 《New Zealand geographer》1999,55(1):66-67

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Factors Controlling Total Concentration and Aqueous Speciation of Aluminium in an Acidic Headwater Stream of the Bavarian Forest National Park: a Modelling Approach     

Ingo Haag  Klaus Moritz  Jochen Bittersohl  Gunnar Lischeid 《洁净——土壤、空气、水》2001,29(4):206-218

The purpose of the present paper is to analyse factors controlling total concentration and aqueous speciation of aluminium in the Große Ohe River, using a thermodynamic equilibrium model and a mixing approach. A model compound for humic substances is derived on the basis of the relation between anion deficit and the organic carbon content in the river as well as literature data. An equilibrium speciation model for aluminium is set up, considering this model compound and relevant inorganic solutes. Although the model cannot be verified directly, its results may be viewed as qualitatively correct. Applying the model to measured stream water samples highlights that aqueous speciation of aluminium is mainly controlled by the pH value and discharge and that free aluminium concentrations reach clearly toxic levels during acidic episodes. Comparing measured concentrations of sulfate and H⁺ and calculated concentrations of Al³⁺ with solubility curves of gibbsite like minerals and jurbanite clearly shows that total aluminium concentrations are not controlled by equilibria with these mineral phases alone. The observed relationship can be better explained from a mixture of two distinct waters, representing lowflow and highflow chemistry, and the resulting equilibrium concentrations. This indicates that total aluminium concentration, in particular during high discharge events, is mainly controlled by the mixture of waters with differing chemistry and flowpaths.  相似文献   

Introduction to the special issue of the 13th International Symposium on River Sedimentation,Stuttgart, Germany: Experimental and measuring/monitoring research related to sediment issues     

Markus Noack  Heide Friedrich  Jochen Aberle 《国际泥沙研究》2018,33(1):1-2

正The papers in this issue stem from the 13th International Symposium on River Sedimentation held in September 2016 at the University of Stuttgart,Germany.The Symposiums on River Sedimentation aim to provide a platform for scientists and engineers for fruitful and in-depth knowledge exchange.The objectives are to develop sustainable revitalization and management strategies that address the ongoing negative effects of anthropogenic activities,whilst improving river systems toward a healthy ecological status.The fundamental research and understanding of interactive  相似文献   

The proximity effect in a close group of QSOs     

J. Liske  G.M. Williger 《Monthly notices of the Royal Astronomical Society》2001,328(2):653-668

We present an analysis of the proximity effect in a sample of 10 2-Å-resolution QSO spectra of the Ly α forest at     . Rather than investigating variations in the number density of individual absorption lines, we employ a novel technique that is based on the statistics of the transmitted flux itself. We confirm the existence of the proximity effect at the > 99 per cent confidence level. We derive a value for the mean intensity of the extragalactic background radiation at the Lyman limit of     . This value assumes that QSO redshifts measured from high-ionization lines differ from the true systemic redshifts by     . We find evidence at a level of 2.6 σ that the significance of the proximity effect is correlated with QSO Lyman limit luminosity. Allowing for known QSO variability, the significance of the correlation reduces to 2.1 σ .
The QSOs form a close group on the sky and the sample is thus well suited for an investigation of the foreground proximity effect, where the Ly α forest of a background QSO is influenced by the UV radiation from a nearby foreground QSO. From the complete sample we find no evidence for the existence of this effect, implying either that     or that QSOs emit at least a factor of 1.4 less ionizing radiation in the plane of the sky than along the line of sight to Earth. We do, however, find one counter-example. Our sample includes the fortunate constellation of a foreground QSO surrounded by four nearby background QSOs. These four spectra all show underdense absorption within ±3000 km s⁻¹ of the redshift of the foreground QSO.  相似文献   

Sediment dynamics in the Eurasian Arctic Ocean during the last deglaciation — The clay mineral group smectite perspective   总被引：1，自引：0，他引：1  

Christoph Vogt  Jochen Knies   《Marine Geology》2008,250(3-4):211-222

This study focuses on sedimentological investigations of sediment cores recovered during the international Arctic′91, expeditions with the German research ice breaker RV “Polarstern” to the European sector of the Arctic Ocean. Here, we deduce the last glacial/interglacial changes in transport mechanism and sedimentation from the clay mineral group smectite. We choose the smectites as an example of how sediment mineralogy can be linked with particular source regions (the Kara and Laptev seas), distinct transport mechanism (sea ice and surface currents) and sedimentation processes. Smectite contents in Arctic sediments discussed for two time slices, including the Last Glacial Maximum (LGM), and the last deglaciation (Termination I), reveal the highest variability subsequent to the retreat of the Eurasian ice sheets. Our results show that smectite anomalies in the Eurasian Basin are associated with distinct meltwater pulses and occurred around 13.5–13.0 ¹⁴C ka B.P. Compelling evidence is provided that these anomalies are deduced from sea-ice entrained sediments from the eastern Kara Sea that entered the Arctic Ocean after ice-sheet break-up and eventually flooding of the Kara Sea. We propose that smectite anomalies in sediments of the eastern Arctic Ocean can be utilized to identify deglacial events and to help decipher configurations of the Eurasian ice sheets. The identification of smectite maxima along the modern sea-ice edge in the Eurasian Basin further indicates biologically enhanced sedimentation from melting sea ice allowing the reconstruction of seasonally open water in the region. Hence, considering the poor preservation conditions of primary paleoceanographic proxies in the Arctic Ocean, the clay mineral contents, particularly the smectite group, may be one alternative tool for paleoclimatic reconstruction in the Eurasian Basin.  相似文献   

Natura 2000 sites and fisheries in German offshore waters     

Pedersen  Soren Anker; Fock  Heino; Krause  Jochen; Pusch  Christian; Sell  Anne L.; Bottcher  Uwe; Rogers  Stuart I.; Skold  Mattias; Skov  Henrik; Podolska  Magdalena; Piet  Gerjan J.; Rice  Jake C. 《ICES Journal of Marine Science》2009,66(1):155-169

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Calibration facility for airborne imaging spectrometers     

Peter Gege  Jochen Fries  Peter Haschberger  Paul Schtz  Horst Schwarzer  Peter Strobl  Birgit Suhr  Gerd Ulbrich  Willem Jan Vreeling 《ISPRS Journal of Photogrammetry and Remote Sensing》2009,64(4):387-397

A new facility designed to perform calibration measurements of airborne imaging spectrometers was established at the German Aerospace Center (DLR) in Oberpfaffenhofen. This Calibration Home Base (CHB) is optimized to characterize radiometrically, spectrally, and geometrically the APEX (Airborne Prism Experiment) imaging spectrometer, which is currently being developed under the authority of the European Space Agency (ESA). It however can be used for other optical sensors as well. Computer control of major laboratory equipment allows automation of time consuming measurements. In APEX configuration (wavelength range: 380 to 2500 nm, instantaneous field of view: 0.48 mrad, field of view: ±14) spectral measurements can be performed to a wavelength uncertainty of ±0.15 nm, geometric measurements at increments of 0.0017 mrad across track and 0.0076 mrad along track, and radiometric measurements to an uncertainty of ±3% relative to national standard. The CHB can be adapted to similar sensors (including those with thermal infrared detectors) by exchanging the monochromator’s lamp, the gratings and the filters, and by adjusting the distance between the sensor and folding mirror.  相似文献